Restructuring Palm Oil's Fat Structure to Replace Butter: Assessing Physicochemical, Composition, and Rheology Changes in Dark, Milk, and White Chocolate Ganache
DOI:
https://doi.org/10.54987/jobimb.v13iSP1.1056Keywords:
Alternative fats, Chocolate compound, Cocoa, Confectionery, EmulsionAbstract
Ganache is made from a combination of chocolate and dairy cream. Dark, milk, and white chocolate compounds can be used to make ganache, in which some of the cocoa butter is replaced with other vegetable fats in the compound chocolate. Palm oil is used as an alternative to butter due to its availability and can help lower the cost of production of confectionery products. Chocolate ganache is prepared with chocolate compound, whipped cream, RBD palm oil, unsalted butter, and inverted sugar, then mixed on a hot plate. This study added 70% and 100% RBD palm oil to the dark, milk, and white chocolate ganache as a substitution for butter. The effect of RBD palm oil on the physicochemical properties of the ganache was evaluated. Several analyses have been done, including pH, moisture content, water activity, colour profile, texture profile, viscosity, and fat analyses. Dark, milk, and white chocolate ganache made with unsalted butter were used as control samples. The addition of RBD palm oil did not significantly affect the pH, moisture content, water activity, and colour of chocolate ganache. This study showed that the dark chocolate ganache with RBD palm oil has the highest viscosity than other samples. It suggests that dark, milk, and white chocolate ganache with 100% RBD palm oil are the preferred formulations due to their viscosity. These three preferred formulations showed the highest percentage of fatty acid at C12:0, C14:0, C16:0, and C18:0. The main distribution of triacylglycerol for these three formulations is on C50 and C52.
References
Kim YJ, Kang S, Kim YJ, Kim WR, Kim YM, Park S. Calorie reduction of chocolate ganache through substitution of whipped cream. J Ethn Foods. 2017; 4(1):51-57. Journal.
Rajah KK., Fats in food technology. 2nd ed. Wiley: West Sussex; 2014. Book.
Lee S, Baek S, Yang S, Lee G. Determination of triacylglycerol composition and its content in refined and fractionated palm oil by using LC-MS/MS with multiple neutral loss scans. J Oil Palm Res. 2023; 46:1-11. Journal.
Bergmann D, O'Connor D, Thümmel A. An analysis of price and volatility transmission in butter, palm oil and crude oil markets. Agric Food Econ. 2016; 4:1-23. Journal.
Izzreen I, Sam KL, Johari K, Fisal A, Noor-Soffalina SS, Maaruf AG. Physicochemical, total phenolic content, antioxidant activity and sensory acceptability of milk and dark cholcolates filled with sacha inchi ganache. Malays. Cocoa J. 2023; 15(2):36-46. Journal.
Izzreen I, Fisal A, Siti-Norizah M. Effect of Hydrocolloids at Different Concentrations on the Physicochemical Properties and Particle Size Distribution of White Chocolate Ganache. Malays. Cocoa J. 2022; 14:173-183. Journal.
Saglio A, Bourgeay J, Socrate R, Canette A, Cuvelier G. Understanding the structure of ganache: Link between composition and texture. Int J Gastron Food Sci. 2018. 13:29-37. Journal.
Maslii Y, Ruban O, Kasparaviciene G, Kalveniene Z, Materiienko A, Ivanauskas L, Mazurkeviciute A, Kopustinskiene DM, Bernatoniene J. The influence of pH values on the rheological, textural and release properties of Carbomer Polacril® 40P-based dental gel formulation with plant-derived and synthetic active components. Molecules, 2020; 25(21):5018. Journal.
Markovic I, Ilic J, Markovic D, Simonovic V, Kosanic N. Color measurement of food products using CIE L* a* b* and RGB color space. J Hyg Eng Des. 2013. Journal.
Dias J, Alvarenga N, Sousa I. Shelf-life of reduced-fat white chocolate fillings using iota-carrageenan. Emir. J. Food Agric. 2017; 29:893-898. Journal.
Dias, J., N. Alvarenga, and I. Sousa, Effect of hydrocolloids on low-fat chocolate fillings. J Food Sci Technol. 2015; 52:7209-7217. Journal.
Kuntom A, Idris A, Ibrahim A, Sue T, Lin W, Ai Y, Board MP. MPOB Test Methods: A compendium of test on palm oil products, palm kernel products, fatty acids, food related products and others. 2005. Book.
Halim RM, Abd Manaf FY. Rapid moisture determination for palm oil products. Info series.
Samsudin SY. Low-fat chocolate spread based on palm oil. MPOB, 2006; 45:27-30. Journal.
Seçuk B, SEÇ?M Y. Development of chili pepper ganache filled chocolate in artisan chocolate production, determination of sensory and physicochemical characteristics. Food Sci Technol. 2021; 42:e01721. Journal.
McGill J, Hartel RW. Investigation into the microstructure, texture and rheological properties of chocolate ganache. J Food Sci. 2018; 83(3):689-699. Journal.
Glicerina V, Balestra F, Dalla Rosa M, Romani S. Microstructural and rheological characteristics of dark, milk and white chocolate: A comparative study. J Food Eng. 2016; 169:165-171. Journal.
Miskandar MS, Man YC, Yusoff MS, Rahman RA. Quality of margarine: fats selection and processing parameters. Asia Pac J Clin Nutr. 2005; 14(4):387. Journal.
Yang D, Lee YY, Lu Y, Wang Y, Zhang Z. Internal Factors Affecting the Crystallization of the Lipid System: Triacylglycerol Structure, Composition, and Minor Components. Molecules 2024; 29(8):1847. Journal.
Wassell P, Young NW. Food applications of trans fatty acid substitutes. Int J Food Sci Technol. 2007; 42(5):503-517. Journal.
Tarmizi AH, Lin SW, Kuntom A. Development of palm-based reference materials for the quantification of fatty acids composition. J Oleo Sci. 2008; 57(5):275-285.
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Copyright (c) 2025 Rafissah Athirah Mohamad Fadzil, Wan Zunairah Wan Ibadullah, Farah Nadiah Abd Rahim, Maslia Manja Badrul Zaman, Izzreen ishak, Johari Khaironi, Nor Afizah Mustapha, Mohammad Rashedi Ismail-Fitry, Radhiah Shukri, Nur Hanani Zainal Abedin, Nor-Khaizura Mahmud Ab Rashid

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