Isothermal Modelling of the Adsorption of Lead (II) Onto Activated Carbon from Tridax procumbens
DOI:
https://doi.org/10.54987/bessm.v6i1.704Keywords:
Biosorption, Lead (II), Isotherm, Antarctic sea-ice bacterial exopolysaccharide, FreundlichAbstract
Hypertension and kidney damage have been linked to lead exposure in adults. Any person can be harmed by lead, but pregnant women and their unborn children are especially vulnerable. Presently, lead pollution is removed using membrane separation, ion exchange, precipitation, and biosorption. Biosorption's low operating costs, high efficiency at detoxifying low concentrations of toxicants, and small volume of disposal materials make it the least problematic of these technologies. The biosorption of lead (II) onto activated carbon from Tridax procumbens is remodeled using nonlinear regression and the optimal mode was determined by a series of error function assessments. The Freundlich model performed best in statistical tests including root-mean-square error (RMSE), adjusted coefficient of determination (adjR2), bias factor (BF), accuracy factor (AF), and corrected Akaike Information Criterion (AICc) The calculated Freundlich parameters kF value using nonlinear regression was 1.334 (1/g) (95% confidence interval from 0.821 to 1.847) and nF value of 3.872 (95% C.I. from 1.972 to 5.771). Modelling using a nonlinear approach allows for the calculation of uncertainty range in terms of 95% confidence interval that would be useful for model comparison and discriminant in future studies
References
Raviraja A, Vishal Babu GN, Sehgal A, Saper RB, Jayawardene I, Amarasiriwardena CJ, et al. Three cases of lead toxicity associated with consumption of ayurvedic medicines. Indian J Clin Biochem. 2010;25(3):326-9.
Alissa EM, Ferns GA. Heavy metal poisoning and cardiovascular disease. J Toxicol. 2011;2011:870125.
Nepalia A, Singh A, Mathur N, Pareek S. Toxicity assessment of popular baby skin care products from Indian market using microbial bioassays and chemical methods. Int J Environ Sci Technol. 2018 Nov 1;15(11):2317-24.
Motulsky HJ, Ransnas LA. Fitting curves to data using nonlinear regression: a practical and nonmathematical review. FASEB J Off Publ Fed Am Soc Exp Biol. 1987;1(5):365-74.
Tran HN, You SJ, Hosseini-Bandegharaei A, Chao HP. Mistakes and inconsistencies regarding adsorption of contaminants from aqueous solutions: A critical review. Water Res. 2017 Sep 1;120:88-116.
Malairajan S. Removal of lead(II) and cadmium(II) ions from wastewater using activated biocarbon. scienceasia. 2011 Jun 1;37115:115-9.
Ridha FN, Webley PA. Anomalous Henry's law behavior of nitrogen and carbon dioxide adsorption on alkali-exchanged chabazite zeolites. Sep Purif Technol. 2009;67(3):336-43.
Langmuir I. The adsorption of gases on plane surfaces of glass, mica and platinum. J Am Chem Soc. 1918;40(9):1361-403.
Freundlich H. Over the adsorption in solution. Z Für Phys Chem. 1906;57:385-470.
Sips R. On the structure of a catalyst surface. J Chem Phys. 1948;16(5):490-5.
Toth J. State equations of the solid-gas interface layers. Acta Chim Acad Sci Hung. 1971;69(3):311-28.
Brunauer S, Emmett PH, Teller E. Adsorption of gases in multimolecular layers. J Am Chem Soc. 1938;60(2):309-19.
Baudu M. Etude des interactions solute-fibres de charbon actif. Application et regeneration. Universite de Rennes I; 1990.
Fritz W, Schluender EU. Simultaneous adsorption equilibria of organic solutes in dilute aqueous solutions on activated carbon. Chem Eng Sci. 1974;29(5):1279-82.
Rohatgi A. WebPlotDigitizer. http://arohatgi.info/WebPlotDigitizer/app/ Accessed June 2 2014.; 2015.
Halmi MIE, Shukor MS, Johari WLW, Shukor MY. Mathematical modelling of the degradation kinetics of Bacillus cereus grown on phenol. J Environ Bioremediation Toxicol. 2014;2(1):1-5.
Khare KS, Phelan Jr FR. Quantitative comparison of atomistic simulations with experiment for a cross-linked epoxy: A specific volume-cooling rate analysis. Macromolecules. 2018;51(2):564-75.
Akaike H. New look at the statistical model identification. IEEE Trans Autom Control. 1974;AC-19(6):716-23.
Burnham KP, Anderson DR. Model Selection and Multimodel Inference: A Practical Information-Theoretic Approach. Springer Science & Business Media; 2002. 528 p.
Kass RE, Raftery AE. Bayes Factors. J Am Stat Assoc. 1995 Jun 1;90(430):773-95.
Ross T, McMeekin TA. Predictive microbiology. Int J Food Microbiol. 1994;23(3-4):241-64.
Barkhordar B, Ghias Aldin M. Comparision of Langmuir and Freundlich equilibriums in Cr, Cu and Ni adsorption by Sargassum. Iran J Environ Health Sci Eng. 2004 Jan 1;1(2):58-64.
Crittenden JC, Watson HM. Adsorption. In: MWH's Water Treatment: Principles and Design, Third Edition [Internet]. John Wiley & Sons, Ltd; 2012 [cited 2020 May 31]. p. 1117-262. Available from: https://onlinelibrary.wiley.com/doi/abs/10.1002/9781118131473.ch15
Foo KY, Hameed BH. Insights into the modeling of adsorption isotherm systems. Chem Eng J. 2010;156(1):2-10.
Al-Ghouti MA, Da'ana DA. Guidelines for the use and interpretation of adsorption isotherm models: A review. J Hazard Mater. 2020 Jul 5;393:122383.
Hu Q, Pang S, Wang D. In-depth Insights into Mathematical Characteristics, Selection Criteria and Common Mistakes of Adsorption Kinetic Models: A Critical Review. Sep Purif Rev. 2021 Jul 1;0(0):1-19.
Baker H. Removal of Lead Ions from Waste Water Using Modified Jordanian Zeolite. Chem Sci Int J. 2020 Nov 9;19-30.
Ahmad R, Mirza A. Synthesis of Guar gum/bentonite a novel bionanocomposite: Isotherms, kinetics and thermodynamic studies for the removal of Pb (II) and crystal violet dye. J Mol Liq. 2018 Jan 1;249:805-14.
Liyanage LMM, Lakmali WGM, Athukorala SNP, Jayasundera KB. Application of live Chlorococcum aquaticum biomass for the removal of Pb(II) from aqueous solutions. J Appl Phycol. 2020 Dec 1;32(6):4069-80.
Yakubu A, Olatunji GA, Adekola FA. Modified/Unmodified Nanoparticle Adsorbents of Cellulose Origin With High Adsorptive Potential for Removal of Pb(II) From Aqueous Solution. Eur Sci J ESJ. 2017 Sep 30;13(27):425-425.
Daifullah A a. M, Moloukhia H. Removal of cobalt and europium radioisotopes using activated carbon prepared from apricot stones. Isot Radiat Res [Internet]. 2002 Jul 1 [cited 2022 Jul 26];34. Available from: https://www.osti.gov/etdeweb/biblio/20395653
Moloukhia H, El-Zakla T, Belacy N. Use of lignocellulosic biomass in removal of 60 Co and 13'4 Cs from radioactive wastewater. Arab J Nucl Sci Appl. 2010;43(1):121-30.
Rajapaksha AU, Vithanage M, Jayarathna L, Kumara CK. Natural Red Earth as a low cost material for arsenic removal: Kinetics and the effect of competing ions. Appl Geochem. 2011 Apr 1;26(4):648-54.
Mahapatra A, Mishra BG, Hota G. Electrospun Fe2O3-Al2O3 nanocomposite fibers as efficient adsorbent for removal of heavy metal ions from aqueous solution. J Hazard Mater. 2013 Aug 15;258-259:116-23.
Sharifi S, Nabizadeh R, Akbarpour B, Azari A, Ghaffari HR, Nazmara S, et al. Modeling and optimizing parameters affecting hexavalent chromium adsorption from aqueous solutions using Ti-XAD7 nanocomposite: RSM-CCD approach, kinetic, and isotherm studies. J Environ Health Sci Eng. 2019 Dec 1;17(2):873-88.
Calderón C, Levío-Raimán M, Diez MC. Cadmium removal for marine food application: comparative study of different adsorbents. Int J Environ Sci Technol [Internet]. 2021 Oct 29 [cited 2022 Jul 26]; Available from: https://doi.org/10.1007/s13762-021-03746-9
Downloads
Published
How to Cite
Issue
Section
License
Copyright (c) 2022 Bulletin of Environmental Science and Sustainable Management (e-ISSN 2716-5353)

This work is licensed under a Creative Commons Attribution 4.0 International License.
Authors who publish with this journal agree to the following terms:
- Authors retain copyright and grant the journal right of first publication with the work simultaneously licensed under a Creative Commons Attribution License (http://creativecommons.org/licenses/by/4.0) that allows others to share the work with an acknowledgement of the work's authorship and initial publication in this journal.
- Authors are able to enter into separate, additional contractual arrangements for the non-exclusive distribution of the journal's published version of the work (e.g., post it to an institutional repository or publish it in a book), with an acknowledgement of its initial publication in this journal.
- Authors are permitted and encouraged to post their work online (e.g., in institutional repositories or on their website) prior to and during the submission process, as it can lead to productive exchanges, as well as earlier and greater citation of published work (See The Effect of Open Access).