Kinetics of the Removal of Polybrominated Diphenyl Ethers from Aqueous Solutions by Using pressure steam–washed Black Tea

Authors

  • 'Izazy Nur Mohd Jaafar Department of Biochemistry, Faculty of Biotechnology and Biomolecular Sciences, Universiti Putra Malaysia, 43400 UPM Serdang, Selangor, D.E, Malaysia.
  • Khalizan Sabullah Biotechnology Programme, Faculty of Science and Natural Resources, Universiti Malaysia Sabah, 88400 Kota Kinabalu, Sabah
  • Ahmad Razi Othman Department of Chemical Engineering, Faculty of Engineering and Built Environment, Universiti Kebangsaan Malaysia, 43600 UKM Bangi, Selangor, D.E, Malaysia.
  • Nur Adeela Yasid Department of Biochemistry, Faculty of Biotechnology and Biomolecular Sciences, Universiti Putra Malaysia, 43400 UPM Serdang, Selangor, D.E, Malaysia.
  • Mohd Izuan Effendi Halmi Department of Soil Management, Faculty of Agriculture, Universiti Putra Malaysia, 43400 UPM Serdang, Selangor, D.E, Malaysia.
  • Mohd Yunus Shukor Department of Biochemistry, Faculty of Biotechnology and Biomolecular Sciences, Universiti Putra Malaysia, 43400 UPM Serdang, Selangor, D.E, Malaysia.

DOI:

https://doi.org/10.54987/jemat.v7i2.493

Keywords:

Biosorption; polybrominated diphenyl ethers; kinetics; pressure steam–washed black tea; pseudo-second order

Abstract

Established approaches for the management of contaminants include things like membrane separation, ion exchange, precipitation, transformation and biosorption. Of all of these technologies, biosorption has lots of features that include low running expenditures, very effective detoxification of toxicants at low levels, low quantity of removal components as well as does not require nutrient needs as with bacterial-based remediation, theaforementioned being restricted to the existence of heavy metals and other toxicants. The biosorption of BDE-3 on spent black tea was successfully fitted to three models—pseudo-1st, pseudo-2nd and Elovich. Statistical analysis based on root-mean-square error (RMSE), adjusted coefficient of determination (adjR2), accuracy factor (AF), bias factor (BF), corrected AICc Bayesian Information Criterion (BIC), (Akaike Information Criterion) and Hannan–Quinn information criterion (HQC) showed that the pseudo-second order model is the best model giving valuable parameters such as the equilibrium sorption capacity qe and the pseudo-second-order rate constant, k2, which can be further utilized in isothermal modelling analysis. Further analysis is needed to provide proof for the chemisorption mechanism usually tied to this kinetic.

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Published

31.12.2019

How to Cite

Jaafar, ’Izazy N. M., Sabullah, K., Othman, A. R., Yasid, N. A., Halmi, M. I. E., & Shukor, M. Y. (2019). Kinetics of the Removal of Polybrominated Diphenyl Ethers from Aqueous Solutions by Using pressure steam–washed Black Tea. Journal of Environmental Microbiology and Toxicology, 7(2), 26–31. https://doi.org/10.54987/jemat.v7i2.493

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