Enhancing Sustainability: Optimisation of Eco-Friendly Corn Starch Based Bioplastic
DOI:
https://doi.org/10.54987/jebat.v8i1.1119Keywords:
Cornstarch, Biofilm, Bioplastics, Pollution, OptimizationAbstract
Plastic is ubiquitous worldwide, and the development of bioplastics necessitates the use of biodegradable and renewable resources. This study focuses on creating and characterizing biodegradable films using varying concentrations of corn starch. The bioplastic films are plasticized with glycerol and citric acid, the latter serving as co-plasticizers in different proportions. Starch concentrations range from 5% to 20% w/v, glycerol concentrations from 5% to 25% v/v, and citric acid content from 1% to 5% w/v. The resulting bioplastics are applied to butter paper to analyse surface morphology, solubility, and water retention. The films blended with glycerol as a plasticizer consistently showed promising results. Introducing citric acid as a co-plasticizer led to a bioplastic film with reduced water retention properties. This study outlines a simple, novel, and cost-effective technique to produce bio-based plastic.
References
Agustin MB, Ahmmad B, Alonzo SM, Patriana FM. Bioplastic based on starch and cellulose nanocrystals from rice straw. J Reinf Plast Compos. 2014;33(24):2205-13.
Azahari NA, Othman N, Ismail H. Biodegradation studies of polyvinyl alcohol/corn starch blend films in solid and solution media. J Phys Sci. 2011;22(2):15-31.
Basiak E, Lenart A, Debeaufort F. Effect of starch type on the physico-chemical properties of edible films. Int J Biol Macromol. 2017;98:348-56.
Bhagwat G, Gray K, Wilson SP, Muniyasamy S, Vincent SG, Bush R, et al. Benchmarking bioplastics: A natural step towards a sustainable future. J Polym Environ. 2020;28:3055-75.
da Rosa Zavareze E, Pinto VZ, Klein B, El Halal SL, Elias MC, Prentice-Hernández C, et al. Development of oxidised and heat-moisture treated potato starch film. Food Chem. 2012;132(1):344-50.
Debet MR, Gidley MJ. Why do gelatinized starch granules not dissolve completely? Roles for amylose, protein, and lipid in granule "ghost" integrity. J Agric Food Chem. 2007;55(12):4752-60.
Gautam N, Kaur I. Soil burial biodegradation studies of starch grafted polyethylene and identification of Rhizobium meliloti therefrom. J Environ Chem Ecotoxicol. 2013;5(6):147-58.
Jiugao Y, Ning W, Xiaofei M. The effects of citric acid on the properties of thermoplastic starch plasticized by glycerol. Starch. 2005;57(10):494-504.
Laohakunjit N, Noomhorm A. Effect of plasticizers on mechanical and barrier properties of rice starch film. Starch. 2004;56(8):348-56.
Lii CY, Shao YY, Tseng KH. Gelation mechanism and rheological properties of rice starch. [Journal details missing - cannot format fully].
Luengo JM, García B, Sandoval A, Naharro G, Olivera ER. Bioplastics from microorganisms. Curr Opin Microbiol. 2003;6(3):251-60.
Lusiana SW, Putri D, Nurazizah IZ. Bioplastic properties of sago-PVA starch with glycerol and sorbitol plasticizers. J Phys Conf Ser. 2019;1351(1):012102.
Marichelvam MK, Jawaid M, Asim M. Corn and rice starch-based bio-plastics as alternative packaging materials. Fibers. 2019;7(4):32.
Mohammed AA, Hasan Z, Omran AA, Elfaghi AM, Khattak MA, Ilyas RA, et al. Effect of various plasticizers in different concentrations on physical, thermal, mechanical, and structural properties of wheat starch-based films. Polymers (Basel). 2022;15(1):63.
Maghfirah A, Sofyan MZ, Siambaton MW, Sitepu SN, Putra OP. The characterization of Porang starch (Amorphophallus oncophyllus) biodegradable plastic using sorbitol plasticizer with glycerol plasticizer addition. J Phys Conf Ser. 2023;2672(1):012001.
Qin Y, Wang W, Zhang H, Dai Y, Hou H, Dong H. Effects of citric acid on structures and properties of thermoplastic hydroxypropyl amylomaize starch films. Materials (Basel). 2019;12(9):1565.
Ratnayake WS, Jackson DS. Gelatinization and solubility of corn starch during heating in excess water: new insights. J Agric Food Chem. 2006;54(10):3712-6.
Beevi KR, Fathima AS, Fathima AT, Thameemunisa N, Noorjahan CM, Deepika T. Bioplastic synthesis using banana peels and potato starch and characterization. Int J Sci Technol Res. 2020;9(1):1809-14.
Santana RF, Bonomo RC, Gandolfi OR, Rodrigues LB, Santos LS, dos Santos Pires AC, et al. Characterization of starch-based bioplastics from jackfruit seed plasticized with glycerol. J Food Sci Technol. 2018;55:278-86.
Sanyang ML, Sapuan SM, Jawaid M, Ishak MR, Sahari J. Effect of plasticizer type and concentration on physical properties of biodegradable films based on sugar palm (Arenga pinnata) starch for food packaging. J Food Sci Technol. 2016;53:326-36.
Shafqat A, Al-Zaqri N, Tahir A, Alsalme A. Synthesis and characterization of starch-based bioplastics using varying plant-based ingredients, plasticizers and natural fillers. Saudi J Biol Sci. 2021;28(3):1739-49.
Safitri A, Sinaga PS, Nasution H, Harahap H, Masyithah Z, Hasibuan R. The role of various plastisizers and fillers additions in improving tensile strength of starch-based bioplastics: A mini review. IOP Conf Ser Earth Environ Sci. 2022;1115(1):012076.
Sultan NF, Johari WL. The development of banana peel/corn starch bioplastic film: A preliminary study. Bioremediat Sci Technol Res. 2017;5(1):12-7.
Willfahrt A, Steiner E, Hötzel J, Crispin X. Printable acid-modified corn starch as non-toxic, disposable hydrogel-polymer electrolyte in supercapacitors. Appl Phys A. 2019;125(7):474.
Wilpiszewska K, Antosik AK, Zdanowicz M. The effect of citric acid on physicochemical properties of hydrophilic carboxymethyl starch-based films. J Polym Environ. 2019;27:1379-87.
Yaradoddi JS, Banapurmath NR, Ganachari SV, Soudagar ME, Sajjan AM, Kamat S, et al. Bio-based material from fruit waste of orange peel for industrial applications. J Mater Res Technol. 2022;17:3186-97.
Yahia R, Owda ME, Abou-Zeid RE, Abdelhai F, El-Gamil HY, Abdo AM, et al. Biodegradable, UV absorber and thermal stable bioplastic films from waxy corn starch/polyvinyl alcohol blends. Biomass Convers Biorefin. 2024;14(22):27989-8006.
Sultan A, Sultan H, Shahzad W, Kareem A, Liaqat A, Ashraf Z, et al. Comparative analysis of physical and mechanical properties of starch-based bioplastic derived from the pulp and peel of potatoes. J Indian Chem Soc. 2024;101(10):101301.
Anitha R, Jayakumar K, Samuel GV, Joice ME, Sneha M, Seeli DS. Synthesis and characterization of starch-based bioplastics: a promising alternative for a sustainable future. Eng Proc. 2024;61(1):30.
Rohidi NN, Othman SA. Investigate the properties of different irradiated starch bioplastic for packaging application. Malays J Sci. 2024;59-71.
Dakarapu SR, Karri SR, Ampolu LS. Mechanical and water absorption properties of polymer composites reinforced with animal bone powder. J Phys Conf Ser. 2023;2604(1):012004.
Folino A, Pangallo D, Calabrò PS. Assessing bioplastics biodegradability by standard and research methods: Current trends and open issues. J Environ Chem Eng. 2023;11(2):109424.
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